Electrochemical behavior of vanadium trichloride in 1-ethyl-3-methyimidazolium chloride-aluminum trichloride molten salt

被引：5

作者：

Katayama, Y ^{[1
]}

Konishiike, I ^{[1
]}

Miura, T ^{[1
]}

Kishi, T ^{[1
]}

机构：

[1] Keio Univ, Fac Sci & Technol, Dept Appl Chem, Kouhoku Ku, Yokohama, Kanagawa 2238522, Japan

来源：

ELECTROCHEMISTRY | 1999年 / 67卷 / 06期

关键词：

1-ethyl-3-methylimidazolium chloride-aluminum trichloride; vanadium trichloride;

D O I：

10.5796/electrochemistry.67.547

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Electrochemical behavior of trivalent vanadium species was investigated in a Lewis basic 1-ethyl-3-methylimidazolium chloride (EMIC)-aluminum trichloride (AlCl3) molten salt at room temperature. The reduction of V(III) was observed around -1.2 V vs. Al(III)/ Al in the cyclic voltammogram on platinum electrode. The reduction process of V(III) seems electrochemically irreversible as observed in aqueous solution.

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页码：547 / 549

页数：3

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