The Stark effect in the v+=1 autoionizing Rydberg states of NO

The Stark effect in autoionizing Rydberg states of NO, n=10-20,v(+)=1, is studied by a combination of experimental and theoretical methods. Double resonant excitation via selected intermediate rotation levels of the A (2)Sigma(+), v'=1 state is carried out in the presence of fields 0-1000 V/cm. The spectra are simulated using both matrix diagonalization and full multichannel quantum defeat theory (MQDT) approaches, providing a test of quantum defect parameters and transition dipoles for Rydberg series from l=0 to l=4. The use of the same input parameters in these two types of calculation allows comparison of the validity and utility of these methods. (C) 2002 American Institute of Physics.