Bis(mu-diphenylphosphinato-O:O')bis(dimethylaluminium)

被引：13

作者：

Corker, JM

Browning, DJ

Webster, M

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195013266

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Al-2(C12H10O2P)(2)(CH3)(4)], contains discrete centrosymmetric molecules each having a slightly puckered eight-membered (Al-O-P-O-)(2) ring. Displacements from the plane of the four O atoms are 0.28 (1) and 0.15 (1) Angstrom for the P and Al atoms, respectively. The Al-O bond distances are 1.781 (3) and 1.794 (3) Angstrom, while the P-O distances are 1.512 (3) and 1.505 (2) Angstrom.

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页码：583 / 585

页数：3

相关论文

共 11 条

[1] TRIMETHYLGALLIUM .PART 4. DIMETHYL-GALLIUM + -ALUMINIUM DERIVATIVES OF SOME OXY- + THIO-ACIDS [J].

COATES, GE ;

MUKHERJEA, RN .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (APR) :1295-&

[2]

Johnson C. K., 1976, ORNL5138

[3]

*MOL STRUCT CORP, 1988, MSC AFC DIFFR CONTR

[4]

*MOL STRUCT CORP, 1992, TEXSAN STRUCT ANAL P

[5] A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].

NORTH, ACT ;

PHILLIPS, DC ;

MATHEWS, FS .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&

[6] INTERACTION OF ORGANIC CARBONYLS WITH STERICALLY CROWDED ARYLOXIDE COMPOUNDS OF ALUMINUM [J].

POWER, MB ;

BOTT, SG ;

CLARK, DL ;

ATWOOD, JL ;

BARRON, AR .

ORGANOMETALLICS, 1990, 9 (12) :3086-3097

[7] ORGANOALUMINUM-PHOSPHINE CHEMISTRY - SYNTHESIS AND MOLECULAR-STRUCTURE OF [PH2P(O)2.ALCL2]2 AND [PH2P.AL(I-BU)2]2 [J].

SANGOKOYA, SA ;

PENNINGTON, WT ;

ROBINSON, GH ;

HRNCIR, DC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 385 (01) :23-31

[8] STUDIES ON DIALKYL METAL PHOSPHORIC AND PHOSPHINIC ACID-DERIVATIVES OF ELEMENTS ALUMINUM, GALLIUM, INDIUM, AND THALLIUM .2. VIBRATIONAL-SPECTRA OF DIFLUOROPHOSPHATES AND DICHLOROPHOSPHATES [J].

SCHAIBLE, B ;

WEIDLEIN, J .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1974, 403 (03) :301-309

[9] STUDIES ON DIALKYL METAL PHOSPHORIC AND PHOSPHINIC ACID-DERIVATIVES OF ELEMENTS ALUMINUM, GALLIUM, INDIUM, AND THALLIUM .1. PREPARATION, PROPERTIES, AND NMR-SPECTRA OF DIALKYL METAL PHOSPHORIC AND PHOSPHINIC ACID-DERIVATIVES [J].

SCHAIBLE, B ;

HAUBOLD, W ;

WEIDLEIN, J .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1974, 403 (03) :289-300

[10] PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES [J].

SHELDRICK, GM .

ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 :467-473