Electrochemical synthesis and crystal structure of (3-trimethylsilylpyridine-2-thiolato)copper(I), [Cu-4(3-Me(3)Sipyt)(4)]

被引：20

作者：

GarciaVasquez, JA

Romero, J

Castro, R

Sousa, A

Rose, DJ

Zubieta, J

机构：

[1] UNIV SANTIAGO DE COMPOSTELA,DEPT QUIM INORGAN,SANTIAGO COMPOSTE 15706,SPAIN

[2] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244

来源：

INORGANICA CHIMICA ACTA | 1997年 / 260卷 / 02期

关键词：

crystal structures; copper complexes; thiolate complexes; tetranuclear complexes; electrochemical synthesis;

D O I：

10.1016/S0020-1693(96)05555-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(3-Trimethylsilyl-pyridine-2-thiolato-S,N)copper(I), [Cu(S-Me(3)Sipyt)], was obtained by electrochemical oxidation of copper metal in an acetonitrile solution of the neutral ligand. The compound is tetrameric and the four copper atoms are arranged with distorted tetrahedral geometry, each copper atom being trigonally coordinated to one nitrogen and two sulfur atoms of three different ligands. Crystal data: I4(1)/a,a=14.608(2), c=19.366(4) Angstrom, V=4133(2), Angstrom 3, Z=4, D-calc=1.581 g cm(-3), R=0.0397 for 848 reflections.

引用

页码：221 / 223

页数：3

共 6 条

[1] 3-SILYLATED AND 3,6-SILYLATED 2-PYRIDINETHIOLS - NEW HINDERED BIDENTATE LIGANDS AND THEIR NOVEL SILVER AND COPPER CLUSTERS [J].