Microwave-assisted synthesis of BaMoO4 nanocrystallites by a citrate complex method and their anisotropic aggregation

被引：37

作者：

Ryu, JH ^{[1
]}

Yoon, JW ^{[1
]}

Shim, KB ^{[1
]}

机构：

[1] Hanyang Univ, Ceram Proc Res Ctr, Dept Ceram Engn, Seoul 133791, South Korea

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2006年 / 413卷 / 1-2期

关键词：

BaMoO4; citrate complex method; anisotropic aggregation; assembling process;

D O I：

10.1016/j.jallcom.2005.07.010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

BaMoO4 powders, which have scheelite-type structure, were successfully synthesized at low temperatures by a modified citrate complex method assisted by microwave irradiation. The citrate complex precursors were heat-treated at temperatures from 300 to 500 degrees C for 3 h. Crystallization of the BaMoO4 powders were detected at 350 degrees C and completed at a temperature of 400 degrees C. TEM image of the BaMoO4 product heat-treated at 400 degrees C revealed spindle-rods-like and flake-like morphology at 500 degrees C. The anisotropic aggregation habit of BaMoO4 lead to two-dimensionally aggregated powder morphology, which was attributed to the high chemical potentials of the intrinsic structure of BaMoO4. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：144 / 149

页数：6

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