Determination of major and trace elements in biological materials by microwave induced plasma optical emission spectrometry (MIP-OES) following tetramethylammonium hydroxide (TMAH) solubilization

被引：46

作者：

Matusiewicz, H ^{[1
]}

Golik, B ^{[1
]}

机构：

[1] Politechnika Poznanska, Dept Analyt Chem, PL-60965 Poznan, Poland

来源：

MICROCHEMICAL JOURNAL | 2004年 / 76卷 / 1-2期

关键词：

multi-element determination; biological reference materials; microwave induced plasma optical emission spectrometry; tetramethy-lammonium; hydroxide solubilization;

D O I：

10.1016/j.microc.2003.10.007

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A simple, alternative method to acid digestion is presented for the preparation of biological materials for major and trace elements by microwave induced plasma optical emission spectrometry (MIP-OES). Standard reference materials were solubilized using a methanolic solution of tetramethylammonium hydroxide (TMAH) by the application of ultrasonic agitation. Following dilution with water suspensions were pumped to a V-groove Babington-type nebulizer then into argon plasma. Limits of detection and precision are reported for major (Na, K, Ca, Mg) and trace (Cu, Fe, Sr, Zn) elements. Standard addition procedures were used to minimize possible matrix interferences. The method offers relatively good precision (R.S.D. ranged from 6 to 12%). Measured concentrations are in satisfactory agreement with certified values for the biological reference materials: TORT-1 (Lobster hepatopancreas), IAEA-153 (Milk powder) and NIST 1577 (Bovine liver). The simple procedure could be useful as a routine analysis of biological materials. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：23 / 29

页数：7

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