Preparation and improvement in the electrical properties of lead-zinc-niobate-based ceramics by thermal treatments

被引:38
作者
Fan, HQ [1 ]
Park, GT [1 ]
Choi, JJ [1 ]
Ryu, J [1 ]
Kim, HE [1 ]
机构
[1] Seoul Natl Univ, Sch Mat Sci & Engn, Seoul 151742, South Korea
关键词
D O I
10.1557/JMR.2002.0027
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The piezoelectric and dielectric properties of Pb(Zn1/3Nb2/3)O-3 (PZN)-based ceramics were investigated. The perovskite structure of PZN ceramics was stabilized by the addition of Pb(Zn0.47Ti0.53)O-3 (PZT). The highest piezoelectric properties were observed for the composition of 0.5PZN-0.5PZT, which lies on the two-phase zone of morphotropic phase boundary. For further improvements in electric properties. the specimens were thermally treated in a flowing O-2 atmosphere at temperatures ranging from 860 to 1030 degreesC. The thermal treatment eliminated the PbO-rich amorphous intergranular layer by lead evaporation. As a result of this improvement in structure, the dielectric constant (epsilon'), the piezoelectric coefficient (d(33)), and the electromechanical coupling factor (k(p)), were enhanced markedly after thermal annealing at 960 degreesC for 8 h in an O-2 atmosphere.
引用
收藏
页码:180 / 185
页数:6
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