Long range ferromagnetism in tunable cobalt(II) layered compounds up to 25 angstrom apart

被引:56
作者
Laget, V [1 ]
Rouba, S [1 ]
Rabu, P [1 ]
Hornick, C [1 ]
Drillon, M [1 ]
机构
[1] UNIV STRASBOURG 1,EHICS,CNRS,UMR 046,IPCMS,GRP MAT INORGAN,F-67037 STRASBOURG,FRANCE
关键词
D O I
10.1016/0304-8853(96)00036-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We discuss the structure-magnetic property correlations for a series of layered cobalt(II) compounds, derived from the parent host Co(OH)(2). Intercalation takes place by exchange of OH- by organic or inorganic anions resulting in interlayer spacing between 4.65 and 25.4 Angstrom. For all the compounds, ferromagnetic in-plane interactions dominate the magnetic behavior at high temperature, but long range order occurs at low temperature; 3d antiferromagnetic order is observed for small basal spacing and ferromagnetic for large spacing. The nature of the magnetic interaction is discussed briefly.
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收藏
页码:L7 / L11
页数:5
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