Kappa-carrageenan-polyethylene oxide hydrogel blends prepared by gamma irradiation

被引:48
作者
Tranquilan-Aranilla, C
Yoshii, F
Dela Rosa, AM
Makuuchi, K
机构
[1] Philippine Nucl Res Inst, Dept Sci & Technol, Quezon 1113, Philippines
[2] Japan Atom Energy Res Inst, Takasaki Radiat Chem Res Estab, Takasaki, Gumma 37012, Japan
关键词
Gamma rays - Hydrogels - Polyethylene oxides - Polymer blends - Swelling;
D O I
10.1016/S0969-806X(98)00317-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
A composite hydrogel system from kappa-carrageenan (KC) and polyethylene oxide was prepared by gamma irradiation, KC was blended with low (LPEO) and medium (MPEO) molecular weight PEO having a concentration of 5% (w/w) at a ratio of 1:1. The properties of the blended hydrogels were evaluated in terms of gel fraction, swelling behavior and gel strength. KC/MPEO hydrogel system has a gel content of 75% at a dose of 10 kGy while 60% gel content was noted for KC/LPEO at the same dose. Water gain of more 10,000% was exhibited by both systems investigated. Gel strength of KC/MPEO was higher compared to KC/LPEO hydrogel. KC/MPEO hydrogel retained 88% (364 N) of its gel strength even after autoclave sterilization. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:127 / 131
页数:5
相关论文
共 6 条
[1]
Mechanical properties of hydrogels and their experimental determination [J].
Anseth, KS ;
Bowman, CN ;
BrannonPeppas, L .
BIOMATERIALS, 1996, 17 (17) :1647-1657
[2]
CATION-SPECIFIC AGGREGATION OF CARRAGEENAN HELICES - DOMAIN MODEL OF POLYMER GEL STRUCTURE [J].
MORRIS, ER ;
REES, DA ;
ROBINSON, G .
JOURNAL OF MOLECULAR BIOLOGY, 1980, 138 (02) :349-362
[3]
NIJENHUIS K, 1997, ADV POLYM SCI, V130, P203
[4]
RADIATION FORMATION OF HYDROGELS FOR BIOMEDICAL PURPOSES - SOME REMARKS AND COMMENTS [J].
ROSIAK, JM ;
ULANSKI, P ;
PAJEWSKI, LA ;
YOSHII, F ;
MAKUUCHI, K .
RADIATION PHYSICS AND CHEMISTRY, 1995, 46 (02) :161-168
[5]
INDUSTRIAL AND NON-FOOD USES FOR CARRAGEENAN [J].
TYE, RJ .
CARBOHYDRATE POLYMERS, 1989, 10 (04) :259-280
[6]
1982, ENCY CHEM TECHNOLOGY