The preparation and microbiological hydroxylation of 10β,11-oxido-4α,5α,7β-eremophilane

被引:12
作者
Arantes, SF [1 ]
Hanson, JR [1 ]
Hitchcock, PB [1 ]
机构
[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England
来源
JOURNAL OF CHEMICAL RESEARCH-S | 1999年 / 05期
关键词
D O I
10.1039/a900186g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The preparation of 10 beta,11-oxido-4 alpha,5 alpha,7 beta-eremophilane by the oxymercuration of valencene, its microbiological hydroxylation at C-1, C-3, C-6, C-7 and C-8 by the fungus, Mucor plumbeus, and the X-ray crystal structures of two of the metabolites, are described.
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页码:314 / 315
页数:3
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