Synthesis and photophysics of tetranuclear copper(I) acetylides. Crystal structure of [Cu-4{P(C(6)H(4)Me-p)(3)}(4)(mu(3)-eta(1)-C CPh)(4)]

被引：63

作者：

Yam, VWW

Lee, WK

Cheung, KK

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 11期

关键词：

D O I：

10.1039/dt9960002335

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of tetranuclear copper(I) acetylide complexes [Cu-4(PR(3))(4)(mu(3)-eta(1)-C=CPh)(4)] (R = Ph 1, C6H4F-(p) 2, C(6)H(4)Me-p 3 or C(6)H(4)OMe-p 4) have been synthesized and shown to exhibit rich photoluminescent behaviour at room temperature. The crystal structure of 3 has also been determined.

引用

页码：2335 / 2339

页数：5

共 50 条

[1] OPTICAL SPECTROSCOPY OF COPPER(I)-DOPED NA+-BETA''-ALUMINA
BARRIE, JD
DUNN, B
HOLLINGSWORTH, G
ZINK, JI
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (10) : 3958 - 3963
[2] SPECTROSCOPY AND X-RAY CRYSTAL-STRUCTURE OF LUMINESCENT PT2(DPPM)2(CN)4[DPPM = BIS(DIPHENYLPHOSPHINO)METHANE]
CHE, CM
YAM, VWW
WONG, WT
LAI, TF
[J]. INORGANIC CHEMISTRY, 1989, 28 (15) : 2908 - 2910
[3] SPECTROSCOPY AND REDOX PROPERTIES OF THE LUMINESCENT EXCITED-STATE OF [AU2(DPPM)2]2+ (DPPM = PH2PCH2PPH2)
CHE, CM
KWONG, HL
POON, CK
YAM, VWW
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (11): : 3215 - 3219
[4] MOLECULES WITH AN M4X4 CORE .11. UNEXPECTED ISOLATION OF THE CUBANE-LIKE ISOMER OF TETRAMERIC (TRIPHENYLARSINE)COPPER(I) IODIDE - CRYSTAL-STRUCTURE OF [(ASPH3)CUI]4.C6H6
CHURCHILL, MR
YOUNGS, WJ
[J]. INORGANIC CHEMISTRY, 1979, 18 (04) : 1133 - 1138
[5] MOLECULES WITH AN M4X4 CORE .3. COMPARISON OF X-RAY CRYSTALLOGRAPHICALLY DETERMINED MOLECULAR-STRUCTURES OF TETRAMERIC TRIETHYLPHOSPHINECOPPER(I) IODIDE AND TRIETHYLARSINECOPPER(I) IODIDE
CHURCHILL, MR
KALRA, KL
[J]. INORGANIC CHEMISTRY, 1974, 13 (08) : 1899 - 1904
[6] MOLECULES WITH AN M4X4 CORE .1. CRYSTAL AND MOLECULAR-STRUCTURE OF TETRAMERIC TRIPHENYLPHOSPHINECOPPER(I) CHLORIDE, A CUBANE-LIKE MOLECULE, INCLUDING LOCATION AND REFINEMENT OF ALL HYDROGEN-ATOMS
CHURCHILL, MR
KALRA, KL
[J]. INORGANIC CHEMISTRY, 1974, 13 (05) : 1065 - 1071
[7] MOLECULES WITH AN M4X4 CORE .5. CRYSTALLOGRAPHIC CHARACTERIZATION OF TETRAMERIC CUBANE-LIKE SPECIES TRIETHYLPHOSPHINECOPPER(I) CHLORIDE AND TRIETHYLPHOSPHINECOPPER(I) BROMIDE - SYSTEMATICS IN [PET3CUX]4 SERIES
CHURCHILL, MR
DEBOER, BG
MENDAK, SJ
[J]. INORGANIC CHEMISTRY, 1975, 14 (09) : 2041 - 2047
[8] De Ahna H. D., 1972, Z. fur Anorg. Allg. Chem, V387, P61, DOI [10.1002/zaac.19723870108, DOI 10.1002/ZAAC.19723870108]
[9] LEWIS-BASE ADDUCTS OF GROUP-1B METAL(I) COMPOUNDS .16. SYNTHESIS, STRUCTURE, AND SOLID-STATE P-31 NUCLEAR MAGNETIC-RESONANCE SPECTRA OF SOME NOVEL [CU4X4L4] (X = HALOGEN, L = N, P BASE) CUBANE CLUSTERS
DYASON, JC
HEALY, PC
ENGELHARDT, LM
PAKAWATCHAI, C
PATRICK, VA
RASTON, CL
WHITE, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (04): : 831 - 838
[10] PHOTOCHEMICAL AND PHOTOPHYSICAL PROPERTIES OF TETRANUCLEAR AND HEXANUCLEAR CLUSTERS OF METALS WITH D10 AND S2 ELECTRONIC CONFIGURATIONS
FORD, PC
VOGLER, A
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (04) : 220 - 226

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