Stepwise, ring-closure synthesis and characterization of a homoleptic palladium(II)-pyrazolato cyclic trimer

被引：44

作者：

Baran, P ^{[1
]}

Marrero, CM ^{[1
]}

Pérez, S ^{[1
]}

Raptis, RG ^{[1
]}

机构：

[1] Univ Puerto Rico, Dept Chem, San Juan, PR 00931 USA

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 09期

关键词：

D O I：

10.1039/b201301k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A triangular homoleptic complex, [Pd(mu-3-Ph-pz)(2)](3), is prepared by the stepwise formation of an open-chain trimer and subsequent ring-closure; D-3 molecular symmetry results from the one-directional arrangement of the unsymmetrically substituted pyrazolato ligands; the palladium atoms are held in close proximity, with Pd-Pd distances of 2.997(1)-3.087(1) Angstrom.

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页码：1012 / 1013

页数：2

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