Acid/base-catalyzed ester hydrolysis in near-critical water

被引：78

作者：

Lesutis, HP

Gläser, R

Liotta, CL

Eckert, CA ^{[1
]}

机构：

[1] Georgia Inst Technol, Sch Chem Engn, Atlanta, GA 30332 USA

[2] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA

[3] Georgia Inst Technol, Specialty Separat Ctr, Atlanta, GA 30332 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 20期

关键词：

D O I：

10.1039/a906401j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrolyses of substituted benzoic acid esters in near-critical water (250-300 degrees C) show autocatalytic kinetic behavior and surprisingly give the same rate constant regardless of substituent, suggesting that an acid-catalyzed mechanism predominates under our reaction conditions.

引用

收藏

页码：2063 / 2064

页数：2

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