Au@pNIPAM Colloids as Molecular Traps for Surface-Enhanced, Spectroscopic, Ultra-Sensitive Analysis

被引:271
作者
Alvarez-Puebla, Ramon A. [1 ,2 ]
Contreras-Caceres, Rafael [3 ]
Pastoriza-Santos, Isabel [1 ,2 ]
Perez-Juste, Jorge [1 ,2 ]
Liz-Marzan, Luis M. [1 ,2 ]
机构
[1] Univ Vigo, Dept Quim Fis, Vigo 36310, Spain
[2] Univ Vigo, Uniclad Asociada CSIC, Vigo 36310, Spain
[3] Univ Almeria, Dept Fis Aplicada, Almeria, Spain
关键词
colloids; gold; nanoparticles; sensing; SERS; POLYCYCLIC AROMATIC-HYDROCARBONS; ULTRASENSITIVE CHEMICAL-ANALYSIS; RAMAN-SCATTERING; GOLD NANOPARTICLES; AG NANOPARTICLES; METAL NANOPARTICLES; OPTICAL-PROPERTIES; PHASE-TRANSITION; SINGLE-MOLECULE; SERS DETECTION;
D O I
10.1002/anie.200804059
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Caught in a trap: Colloids of gold nanoparticles coated with a thermally responsive poly-(N-isopropylacrylamide) (pNIPAM) microgel can trap molecules in different ways as a function of temperature (see scheme). The porous pNIPAM shells prevent electromagnetic coupling between metal particles, thus providing highly reproducible surface-enhanced Raman scattering (SERS) signals and intensity. (Figure Presented). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:138 / 143
页数:6
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