Controlled/living radical polymerization in aqueous media: homogeneous and heterogeneous systems

被引:537
作者
Qiu, J
Charleux, B
Matyjaszewski, K
机构
[1] Carnegie Mellon Univ, Dept Chem, Ctr Macromol Engn, Pittsburgh, PA 15213 USA
[2] Univ Paris 06, Lab Chim Macromol, CNRS, UMR 7610,Unite Mixte Associee, F-75252 Paris 05, France
基金
美国安德鲁·梅隆基金会;
关键词
aqueous solution; suspension; emulsion; miniemulsion; nitroxide; atom transfer radical polymerization; reversible transfer; reversible addition-fragmentation transfer;
D O I
10.1016/S0079-6700(01)00033-8
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Controlled/living radical polymerizations carried out in the presence of water have been examined. These aqueous systems include both the homogeneous solutions and the various heterogeneous media, namely dispersion, suspension, emulsion and miniemulsion. Among them, the most common methods allowing control of the radical polymerization, such as nitroxide-mediated polymerization, atom transfer radical polymerization and reversible transfer, are presented in detail. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2083 / 2134
页数:52
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