OH-O and CH-O hydrogen bonding in hydrated crystals of paramagnetic [(eta(6)-C6H6)(2)Cr](+)

被引:34
作者
Braga, D
Costa, AL
Grepioni, F
Scaccianoce, L
Tagliavini, E
机构
[1] Dipartimento di Chimica G. Ciamician, Università di Bologna, 40126 Bologna
关键词
D O I
10.1021/om950611d
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The hydrated crystalline species [(eta(6)-C6H6)(2)-Cr][OH]. 3H(2)O and [(eta(6)-C6H6)(2)Cr][CHD]. 3H(2)O (CHD=1,3-cyclohexanedione) have been prepared and structurally characterized, showing that OH-O as well as CH-O hydrogen bonds involving the water molecules are responsible for crystal cohesion.
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页码:1084 / 1086
页数:3
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