An experimental study of the gas-phase reactions of the NO3 radical with pent-1-ene, hex-1-ene and hept-1-ene

被引：24

作者：

Canosa-Mas, CE ^{[1
]}

King, MD ^{[1
]}

McDonnell, L ^{[1
]}

Wayne, RP ^{[1
]}

机构：

[1] Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1999年 / 1卷 / 11期

关键词：

D O I：

10.1039/a900870e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rate coefficients for the reactions between the NO3 radical and pent-1-ene (k(1)), hex-1-ene (k(2)) and hept-1-ene (k(3)) have been determined at T = 296 +/- 1 K and P = 759 +/- 7 Torr by a relative-rate method using the reaction between the NO3 radical and but-1-ene (k(4)) as the reference reaction. The values of the rate constants measured were k(1) = (1.51 +/- 0.54) x 10(-14) cm(3) molecule(-1) s(-1), k(2) = (1.85 +/- 0.66) x 10(-14) cm(3) molecule(-1) s(-1), k(3) = (2.06 +/- 0.62) x 10(-14) cm(3) molecule(-1) s(-1) and the value of the reference rate constant was k(4) = (1.35 +/- 0 41) x 10(-14) cm(3) molecule(-1) s(-1).

引用

页码：2681 / 2685

页数：5

共 20 条

[1] KINETICS AND MECHANISMS OF THE GAS-PHASE REACTIONS OF THE HYDROXYL RADICAL WITH ORGANIC-COMPOUNDS UNDER ATMOSPHERIC CONDITIONS [J].