Raman and FTIR spectra of [Cu(H2O)6](BrO3)2 and [Al(H2O)6](BrO3)3•3H2O

Raman and FTIR spectra of [Cu(H2O)(6)](BrO3)(2) and [Al(H2O)(6)](BrO3)(3) (.) 3H(2)O are recorded and analyzed. The observed bands are assigned on the basis of BrO3- and H2O vibrations. Additional bands obtained in the region of v(3) and v(1) modes in [Cu(H2O)(6)](BrO3)(2) are due to the lifting of degeneracy of v(3) modes, since the BrO3- ion occupies a site of lower symmetry. The appearance v(1) mode of BrO3- anion at a lower wavenumber (771 cm(-1)) is attributed to the attachment of hydrogen to the BrO3- anion. The presence of three inequivalent bromate groups in the [Al(H2O)(6)](BrO3)(3)(.)3H(2)O structure is confirmed. The lifting of degeneracy of v(4) mode indicates that the symmetry of BrO3- anion is lowered in the above crystal from C-3v to C-1. The appearance of additional bands in the stretching and bonding mode regions of water indicates the presence of hydrogen bonds of different strengths in both the crystals. Temperature dependent Raman spectra of single crystal [Cu(H2O)(6)](BrO3)(2) are recorded in the range 77-523 K for various temperatures. A small structural rearrangement takes place in BrO3- ion in the crystal at 391 K. Hydrogen bounds in the crystal are rearranging themselves leading to the loss of one water molecule at 485 K. This is preceded by the reorientation of BrO3- ions causing a phase transition at 447 K. Changes in intensities and wavenumbers of the bands and the narrowing down of the bands at 77 K are attributed to the settling down of protons into ordered positions in the crystal. (C) 2002 Elsevier Science B.V. All rights reserved.