Metal-insulator transition in the organic metal (TTM-TTP)I-3 with a one-dimensional half-filled band

被引:60
作者
Mori, T
Kawamoto, T
Yamaura, J
Enoki, T
Misaki, Y
Yamabe, T
Mori, H
Tanaka, S
机构
[1] TOKYO INST TECHNOL,DEPT CHEM,TOKYO 152,JAPAN
[2] KYOTO UNIV,GRAD SCH ENGN,DIV MOL ENGN,KYOTO 60601,JAPAN
[3] INT SUPERCONDUCT TECHNOL CTR,TOKYO 135,JAPAN
关键词
D O I
10.1103/PhysRevLett.79.1702
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The title 1:1 composition organic conductor, with a highly one-dimensional half-filled energy band, exhibits metallic conductivity down to T-MI approximate to 160 K, but the spin susceptibility follows the one-dimensional Heisenberg model from room temperature to 2 K, without any anomaly at TMI. The insulating state is regarded as a Mott insulator. The small U, related to the extended molecular structure, gives rise to the small charge gap and the high-temperature metallic conduction.
引用
收藏
页码:1702 / 1705
页数:4
相关论文
共 9 条
[1]  
HARTFIELD WE, 1983, EXTENDED LINEAR CHAI, V3, P43
[2]  
JEROME D, 1995, SYNTHETIC MET, V70, P719, DOI 10.1016/0379-6779(94)02630-H
[3]   THE PHYSICS OF ORGANIC SUPERCONDUCTORS [J].
JEROME, D .
SCIENCE, 1991, 252 (5012) :1509-1514
[4]  
LAVERSANNE R, 1984, J PHYS LETT-PARIS, V45, pL393, DOI 10.1051/jphyslet:01984004508039300
[5]  
MISAKI Y, 1992, CHEM LETT, V1993, P2321
[6]  
MORI H, 1996, SYNTHETIC MET, V284, P15
[7]   CRYSTAL-STRUCTURES OF HIGHLY CONDUCTING IODINE COMPLEXES OF TTM-TTP [J].
MORI, T ;
INOKUCHI, H ;
MISAKI, Y ;
YAMABE, T ;
MORI, H ;
TANAKA, S .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1994, 67 (03) :661-667
[8]   CORRELATED FERMIONS IN 1 DIMENSION [J].
SCHULZ, HJ .
INTERNATIONAL JOURNAL OF MODERN PHYSICS B, 1991, 5 (1-2) :57-74
[9]   REFLECTANCE SPECTRA OF BIS-FUSED TTF RADICAL-CATION SALTS [J].
TAJIMA, H ;
ARIFUKU, M ;
OHTA, T ;
MORI, T ;
MISAKI, Y ;
YAMABE, T ;
MORI, H ;
TANAKA, S .
SYNTHETIC METALS, 1995, 71 (1-3) :1951-1952