A Route for Lignin and Bio-Oil Conversion: Dehydroxylation of Phenols into Arenes by Catalytic Tandem Reactions

被引：238

作者：

Wang, Xingyu ^{[1
]}

Rinaldi, Roberto ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Ruhr, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 44期

关键词：

arenes; biomass; heterogeneous catalysis; nickel; synthetic methods; O BOND-CLEAVAGE; HYDROXY-GROUPS; ARYL ETHERS; REDUCTIVE REMOVAL; HYDROGENOLYSIS; NICKEL; HYDRODEOXYGENATION; DEPOLYMERIZATION; SPECTROSCOPY; DERIVATIVES;

D O I：

10.1002/anie.201304776

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Finding a workaround: The conversion of lignin into low-boiling-point arenes instead of high-boiling-point phenols could greatly facilitate conventional refinery processes. A new procedure for the depolymerization of lignin and simultaneous conversion phenols into arenes is described. The method can also be rendered as a fundamental finding for the upgrade of bio-oils to arenes under mild conditions. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11499 / 11503

页数：5

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