Synthesis and ion binding properties of a p-keto-oxime and a vic-dioxime derivative of calix[6]arene

被引：14

作者：

Deligoz, H ^{[1
]}

Yilmaz, M ^{[1
]}

机构：

[1] SELCUK UNIV,DEPT CHEM,KONYA 42079,TURKEY

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1996年 / 26卷 / 06期

关键词：

D O I：

10.1080/00945719608004345

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A keto-oxime derivative of calix[6]arene was synthesized from 5,11,17,23,29,35-hexaacetyl-37,38,39,40,41,42-hexamethoxycalix[6]arene by oxidation of the CH3 group of the acetyl groups to isonitroso groups. The prepared compound was converted into its vic-dioxime derivative by treatment with NH2OH.HCl. The resulting ligands (2, 3) were treated with three transition metal salts (e.g., CuCl2.2H(2)O, NiCl2.6H(2)O or CoCl2.6H(2)O). While the Cu(II), Ni(II) and Co(II) complexes of the vic-dioxime derivative of calix[6]arene were obtained, only Co(II) gave a complex with the keto-oxime derivative of calix[6]arene. All the complexes have a metal-ligand ratio of 3:1. The Cu(II) and NI(II) complexes of 3 are square-planar, while the Co(II) complex of both ligands are octahedral with water molecules as axial ligands.

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页码：943 / 953

页数：11

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