An improved and efficient procedure for the preparation of chiral sulfinates from sulfonyl chloride using triphenylphosphine

被引:30
作者
Watanabe, Y [1 ]
Mase, N [1 ]
Tateyama, M [1 ]
Toru, T [1 ]
机构
[1] Nagoya Inst Technol, Dept Appl Chem, Showa Ku, Nagoya, Aichi 4668555, Japan
关键词
D O I
10.1016/S0957-4166(99)00066-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
An improved procedure of the Sharpless method for the preparation of chiral sulfinates by triphenylphosphine is described. A mixture of sulfonyl chlorides and diacetone-D-glucose or l-menthol in the presence of triethylamine was treated with triphenylphosphine in CH2Cl2 at 0 degrees C to give the sulfinates in good yields. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:737 / 745
页数:9
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