High-frequency EPR: an occasion for revisiting ligand field theory

被引：23

作者：

Gatteschi, D

Sorace, L

Sessoli, R

Barra, AL

机构：

[1] Univ Florence, Dipartimento Chim, I-50019 Fiorentino, Firenze, Italy

[2] Consorzio Interuniv Nazl Sci & Tecnol Mat, Unita Ric, Fiorentino, Firenze, Italy

[3] CNRS, Grenoble High Magnet Field Lab, F-38042 Grenoble, France

[4] Max Planck Inst Festkorperphys, Grenoble, France

来源：

APPLIED MAGNETIC RESONANCE | 2001年 / 21卷 / 3-4期

关键词：

D O I：

10.1007/BF03162409

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The use of high-field electron paramagnetic resonance (EPR) made possible for the first time to obtain detailed information on the anisotropy of integer-spin systems, which are usually silent at conventional EPR frequencies. The data obtained so far by different research groups on non-Kramers ions are reviewed within the framework of ligand field theory at different levels of approximations. Special attention is paid to the use of the angular overlap model, which resulted to be very powerful both in terms of qualitative and quantitative explanation of the experimental results.

引用

页码：299 / 310

页数：12

共 32 条

[1]

Abragam A., 1986, ELECT PARAMAGNETIC R

[2]

[Anonymous], 1982, TRANSIT METAL CHEM

[3]

Ballhausen C. J., 1962, INTRO LIGAND FIELD T

[4] SPECTRAL-STRUCTURAL CORRELATIONS IN HIGH-SPIN COBALT(II) COMPLEXES [J].