Metal complexes of bibracchial Schiff base macrocycles

被引：285

作者：

Collinson, SR ^{[1
]}

Fenton, DE ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

COORDINATION CHEMISTRY REVIEWS | 1996年 / 148卷

关键词：

D O I：

10.1016/0010-8545(95)01156-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This article discusses polynuclear metal complexes of Schiff base macrocycles and their potential application to the modelling of metallobiosites, in particular di- and tri-nuclear copper(II)-containing sites. A brief perspective of the area is presented and then the article addresses the development of pyridinyl-derived bibracchial (doubly pendant-armed) Schiff base macrocycles and their metal complexes. The cleft-like configurations of the complexes bear resemblance to the metal-containing pockets present in metalloproteins. A 'first generation' model for the trinuclear copper site in ascorbate oxidase, and a dinuclear manganese(II) complex bearing a single acetato-bridge, and which may have relevance to the modelling of dinuclear manganese biosites, are discussed. An extension of the work to thiophene-derived macrocycles and their dicopper(I) complexes is also presented.

引用

页码：19 / 40

页数：22

共 67 条

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