Cosynthesis, coexistence, and self-organization of α- and β-cobalt hydroxide based on diffusion and reaction in organic gels

被引：38

作者：

El-Batlouni, Hazar ^{[1
]}

El-Rassy, Houssam ^{[1
]}

Al-Ghoul, Mazen ^{[1
]}

机构：

[1] Amer Univ Beirut, Dept Chem, Beirut 11072020, Lebanon

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2008年 / 112卷 / 34期

关键词：

D O I：

10.1021/jp804569b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the cosynthesis of highly stable laminated single crystal alpha- and beta-Co(OH)(2) using the reaction and diffusion of a hydroxide solution into a gel containing Co(II). The obtained alpha-Co(OH)(2), which is known to be thermodynamically unstable and transforms in a short period of time to the P form, has been stabilized in the gel medium for weeks. The system also exhibits Liesegang banding where complicated spatial dynamics during the formation of the two polymorphs are shown to take place.

引用

页码：7755 / 7757

页数：3

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