Solid channel structure and nanoscale drum-like Ag6 cluster constructed with pentafluorobenzenethiolate and triphenylphosphine ligands:: The use of water-soluble silver(I) carboxylate as silver(I) source

被引：19

作者：

Noguchi, R ^{[1
]}

Hara, A ^{[1
]}

Sugie, A ^{[1
]}

Nomiya, K ^{[1
]}

机构：

[1] Kanagawa Univ, Fac Sci, Dept Mat Sci, Hiratsuka, Kanagawa 2591293, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 01期

关键词：

nanoscale hexanuclear silver(I) cluster; solid channel structure; pentafluorobenzenethiol; triphenylphosphine; 2-pyrrolidone-5-carboxylic acid;

D O I：

10.1016/j.inoche.2005.10.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A nanoscale drum-like hexanuclear silver(l) cluster [Ag(pfbt)(PPh3)](6) 1 (Hpfbt = pentafluorobenzenethiol), which showed the arrays of channels based on its self-assembly in the solid, was obtained by the 1: 1 molar-ratio reaction of the insoluble polymeric precursor(infinity)[Ag(pfbt)](2) and PPh3 in chloroform. Synthetic yield and purity of 1 were strongly dependent on the purity of 2. Compound 2 with higher purity was prepared in good yield using light-stable and water-soluble silver(l) carboxylate [Ag(Hpyrrld)](2) (H(2)pyrrld = 2-pyrrolidone-5-carboxylic acid) as the silver(I) source. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：60 / 63

页数：4

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