Conjugated main-group polymers for optoelectronics

被引：149

作者：

He, Xiaoming ^{[1
]}

Baumgartner, Thomas

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

来源：

RSC ADVANCES | 2013年 / 3卷 / 29期

基金：

加拿大自然科学与工程研究理事会;

关键词：

BAND-GAP; ORGANOBORON POLYMERS; BUILDING-BLOCK; HYDROBORATION POLYMERIZATION; OPTICAL-PROPERTIES; PI-CONJUGATION; SOLAR-CELLS; PHOSPHOLE; LUMINESCENT; SYSTEMS;

D O I：

10.1039/c3ra40286j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The last decade has witnessed great progress in conjugated polymers for application in optoelectronics. The biggest driving force for the field is to develop polymers with suitable HOMO and LUMO orbital energies, as well as high charge carrier mobility for improved performance in practical devices. Apart from the conventional donor-acceptor (D-A) strategy to tune the optoelectronic properties, the incorporation of main-group elements represents a promising new way to achieve a similar function, however, more efficiently, due to the intrinsic electronic properties of the main-group components. This review highlights the recent advances in main-group element-based conjugated polymers for application in optoelectronics, representatively focusing on Se-, Te-, P-, Si-, Ge-, and B-containing materials.

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收藏

页码：11334 / 11350

页数：17

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