A Simple Chemical Route toward Monodisperse Iron Carbide Nanoparticles Displaying Tunable Magnetic and Unprecedented Hyperthermia Properties

被引:171
作者
Meffre, Anca [1 ]
Mehdaoui, Boubker [1 ]
Kelsen, Vinciane [1 ]
Fazzini, Pier Francesco [1 ]
Carrey, Julian [1 ]
Lachaize, Sebastien [1 ]
Respaud, Marc [1 ]
Chaudret, Bruno [1 ]
机构
[1] Univ Toulouse, INSA, Lab Phys & Chim Nano Objets, F-31077 Toulouse, France
关键词
Magnetic nanoparticles; iron carbides; iron; core/shell; hyperthermia; organometallic chemistry; SUPERLATTICES; STABILIZATION; SIZE; FE;
D O I
10.1021/nl302160d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report a tunable organometallic synthesis of monodisperse iron carbide and core/shell iron/iron carbide nanoparticles displaying a high magnetization and good air-stability. This process based on the decomposition of Fe(CO)(5) on Fe(0) seed:, allows the control of the amount of carbon diffused and therefore the tuning of nanoparticles magnetic anisotropy. This results in unprecedented hyperthermia properties at moderate magnetic fields, in the range of medical treatments.
引用
收藏
页码:4722 / 4728
页数:7
相关论文
共 36 条
[1]   Magnetic Nanoparticles of Iron Carbide, Iron Oxide, Iron@Iron Oxide, and Metal Iron Synthesized by Laser Ablation in Organic Solvents [J].
Amendola, Vincenzo ;
Riello, Pietro ;
Meneghetti, Moreno .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (12) :5140-5146
[2]   Interface Effects on the Magnetism of CoPt-Supported Nanostructures [J].
Barcaro, Giovanni ;
Sementa, Luca ;
Negreiros, Fabio R. ;
Ferrando, Riccardo ;
Fortunelli, Alessandro .
NANO LETTERS, 2011, 11 (12) :5542-5547
[3]   Simple models for dynamic hysteresis loop calculations of magnetic single-domain nanoparticles: Application to magnetic hyperthermia optimization [J].
Carrey, J. ;
Mehdaoui, B. ;
Respaud, M. .
JOURNAL OF APPLIED PHYSICS, 2011, 109 (08)
[4]   Architecture of Metallic Nanostructures: Synthesis Strategy and Specific Applications [J].
Chen, Hao Ming ;
Liu, Ru-Shi .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (09) :3513-3527
[5]   One-pot synthesis of core - Shell FeRh nanoparticles [J].
Ciuculescu, Diana ;
Amiens, Catherine ;
Respaud, Marc ;
Falqui, Andrea ;
Lecante, Pierre ;
Benfield, Robert E. ;
Jiang, Linqin ;
Fauth, Kai ;
Chaudret, Bruno .
CHEMISTRY OF MATERIALS, 2007, 19 (19) :4624-4626
[6]   Nanoscale chemical imaging of a working catalyst by scanning transmission X-ray microscopy [J].
de Smit, Emiel ;
Swart, Ingmar ;
Creemer, J. Fredrik ;
Hoveling, Gerard H. ;
Gilles, Mary K. ;
Tyliszczak, Tolek ;
Kooyman, Patricia J. ;
Zandbergen, Henny W. ;
Morin, Cynthia ;
Weckhuysen, Bert M. ;
de Groot, Frank M. F. .
NATURE, 2008, 456 (7219) :222-U39
[7]   Multimillimetre-large superlattices of air-stable iron-cobalt nanoparticles [J].
Desvaux, C ;
Amiens, C ;
Fejes, P ;
Renaud, P ;
Respaud, M ;
Lecante, P ;
Snoeck, E ;
Chaudret, B .
NATURE MATERIALS, 2005, 4 (10) :750-753
[8]   Superlattices of iron nanocubes synthesized from Fe[N(SiMe3)2]2 [J].
Dumestre, F ;
Chaudret, B ;
Amiens, C ;
Renaud, P ;
Fejes, P .
SCIENCE, 2004, 303 (5659) :821-823
[9]   Size-sorted anionic iron oxide nanomagnets as colloidal mediators for magnetic hyperthermia [J].
Fortin, Jean-Paul ;
Wilhelm, Claire ;
Servais, Jacques ;
Menager, Christine ;
Bacri, Jean-Claude ;
Gazeau, Florence .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (09) :2628-2635
[10]   Supported Iron Nanoparticles as Catalysts for Sustainable Production of Lower Olefins [J].
Galvis, Hirsa M. Torres ;
Bitter, Johannes H. ;
Khare, Chaitanya B. ;
Ruitenbeek, Matthijs ;
Dugulan, A. Iulian ;
de Jong, Krijn P. .
SCIENCE, 2012, 335 (6070) :835-838