Dissociation of CH4 at high pressures and temperatures:: Diamond formation in giant planet interiors?

被引:173
作者
Benedetti, LR [1 ]
Nguyen, JH
Caldwell, WA
Liu, HJ
Kruger, M
Jeanloz, R
机构
[1] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Dept Geol & Geophys, Berkeley, CA 94720 USA
[3] Univ Calif Berkeley, Dept Astron, Berkeley, CA 94720 USA
[4] Univ Calif Berkeley, Miller Inst Basic Res Sci, Berkeley, CA 94720 USA
[5] Univ Calif Lawrence Livermore Natl Lab, Phys Directorate, Div H, Livermore, CA 94551 USA
[6] Univ Missouri, Dept Phys, Kansas City, MO 64110 USA
关键词
D O I
10.1126/science.286.5437.100
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Experiments using Laser-heated diamond anvil cells show that methane (CH4) breaks down to form diamond at pressures between 10 and 50 gigapascals and temperatures of about 2000 to 3000 kelvin. Infrared absorption and Raman spectroscopy, along with x-ray diffraction, indicate the presence of polymeric hydrocarbons in addition to the diamond, which is in agreement with theoretical predictions, Dissociation of CH4 at high pressures and temperatures can influence the energy budgets of planets containing substantial amounts of CH4, water, and ammonia, such as Uranus and Neptune.
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页码:100 / 102
页数:3
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