Nanoparticle-copolymer composites: Curvature

被引:8
作者
Hamdoun, B [1 ]
Ausserre, D [1 ]
Joly, S [1 ]
机构
[1] UNIV MAINE,LAB PHYS ETAT CONDENSE,URA CNRS 807,F-72017 LE MANS,FRANCE
来源
JOURNAL DE PHYSIQUE II | 1996年 / 6卷 / 08期
关键词
D O I
10.1051/jp2:1996125
中图分类号
O3 [力学];
学科分类号
08 ; 0801 ;
摘要
The compression coefficient and the mean curvature coefficient of a composite of an A-B diblock copolymer charged with nanoparticles depend on the concentration of nanoparticles and on the dissymmetry of the copolymer chains. Concerning the curvature coefficient, a distinction must be done between an adiabatic and an isotherm coefficient when the copolymer chains are not symmetric or when Phi is not zero. Finally, the AB interfaces of the composite film present a spontaneous curvature that we calculate in the approximation of ''small'' nanoparticles.
引用
收藏
页码:1207 / 1217
页数:11
相关论文
共 8 条
  • [1] ADSORPTION OF CHAIN MOLECULES WITH A POLAR HEAD A-SCALING DESCRIPTION
    ALEXANDER, S
    [J]. JOURNAL DE PHYSIQUE, 1977, 38 (08): : 983 - 987
  • [2] CONFORMATIONS OF POLYMERS ATTACHED TO AN INTERFACE
    DEGENNES, PG
    [J]. MACROMOLECULES, 1980, 13 (05) : 1069 - 1075
  • [3] New nanocomposite materials
    Hamdoun, B
    Ausserre, D
    Joly, S
    Gallot, Y
    Cabuil, V
    Clinard, C
    [J]. JOURNAL DE PHYSIQUE II, 1996, 6 (04): : 493 - 501
  • [4] Copolymer nanoparticle composites: Lamellar period
    Hamdoun, B
    Ausserre, D
    Cabuil, V
    Joly, S
    [J]. JOURNAL DE PHYSIQUE II, 1996, 6 (04): : 503 - 510
  • [5] HAMDOUN B, 1995, THESIS LE MANS FRANC
  • [6] BLOCK COPOLYMER THEORY .4. NARROW INTERPHASE APPROXIMATION
    HELFAND, E
    WASSERMAN, ZR
    [J]. MACROMOLECULES, 1976, 9 (06) : 879 - 888
  • [7] SEMENOV AN, 1985, ZH EKSP TEOR FIZ, V61, P733
  • [8] EQUILIBRIUM EMULSIFICATION OF POLYMER BLENDS BY DIBLOCK COPOLYMERS
    WANG, ZG
    SAFRAN, SA
    [J]. JOURNAL DE PHYSIQUE, 1990, 51 (02): : 185 - 200