A novel chiral terpyridine macrocycle as a fluorescent sensor for enantioselective recognition of amino acid derivatives

被引：105

作者：

Wong, WL

Huang, KH

Teng, PF

Lee, CS

Kwong, HL

机构：

[1] City Univ Hong Kong, Dept Biol & Chem, Kowloon Tong, Hong Kong, Peoples R China

[2] City Univ Hong Kong, Inst Mol Technol Drugs Discovery & Synth, Open Lab Chirotechnol, Kowloon Tong, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 04期

关键词：

D O I：

10.1039/b313960c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Terpyridine macrocycle 1 is shown to be a strong chelating agent for organic ammonium salts and also a useful chromophore in fluorescent sensing. It exhibits very good enantioselectivity (K-obs (S)/K-obs, (R)=3.8) in chiral discrimination of alpha-phenylglycine methyl ester hydrochloride (PhEtOMe).

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页码：384 / 385

页数：2

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