Silyl group transfer from allylsilanes to olefins catalyzed by a ruthenium(II) complex

被引：31

作者：

Kakiuchi, F

Yamada, A

Chatani, N

Murai, S ^{[1
]}

Furukawa, N

Seki, Y

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Osaka 5650871, Japan

[2] Kagawa Univ, Fac Econ, Lab Commod Sci, Kagawa 7608523, Japan

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 10期

关键词：

D O I：

10.1021/om9810450

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dehydrogenative silylation of olefins, such as styrenes, methyl acrylate, and vinyl ether, using allyltriethoxysilane as the source of the silyl group can be catalyzed by RuHCl(CO)(PPh3)(3) to give the corresponding vinylsilanes in good to excellent yields. The ruthenium complex also catalyzed the self-dehydrogenative silylation of allylsilanes, yielding 1,3-bis(triorganosilyl)propenes.

引用

页码：2033 / 2036

页数：4

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