Aquabis(tetrahydrofuran)hexakis(trifluoroacetato)(μ3-oxo)zinc(II)diiron(III)

被引：4

作者：

Amini, MM

Yadavi, M

Ng, SW ^{[1
]}

机构：

[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

[2] Shahid Beheshti Univ, Dept Chem, Tehran, Iran

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536804006774

中图分类号：

O7 [晶体学];

学科分类号：

0702 [物理学]; 070205 [凝聚态物理]; 0703 [化学]; 080501 [材料物理与化学];

摘要：

In the oxo- centered compound, [ ZnFe2O(O2CCF3) (6)- ( C4H8O)(2)( H2O)], the central O atom is linked to three metal atoms, which are themselves each linked to four trifluoroacetate anions and are in a triangular configuration. Two of the metal atoms are each coordinated by a tetrahydrofuran molecule, whereas the third is coordinated by a water molecule. Two [ ZnFe2O( O2CCF3) (6)( C4H8O) (2)( H2O)] units are linked by a pair of hydrogen bonds across a center of inversion to afford a hydrogen- bonded dimer. The compound is isostructural with the Cu-II Fe-2(III) analog.

引用

页码：M495 / M497

页数：3