Cathode properties of Na2C6O6 for sodium-ion batteries

被引:111
作者
Chihara, Kuniko [1 ]
Chujo, Nobuhito [2 ]
Kitajou, Ayuko [3 ]
Okada, Shigeto [1 ]
机构
[1] Kyushu Univ, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168580, Japan
[2] Kyushu Univ, Dept Appl Sci Elect & Mat, Kasuga, Fukuoka 8168580, Japan
[3] Kyushu Univ, Res & Educ Ctr Carbon Resources, Kasuga, Fukuoka 8168580, Japan
关键词
Sodium-ion battery; Organic material; Disodium rhodizonate; ANODE MATERIAL; HIGH-CAPACITY; TEREPHTHALATE; ELECTRODE; POLYMERS; NA;
D O I
10.1016/j.electacta.2013.04.100
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
For sodium-ion battery, cathode properties of disodium rhodizonate, Na2C6O6, were investigated. Unlike other organic active materials, Na2C6O6 exhibited good rechargeable capacity about 270 mAh g(-1), corresponding to more than 2 Na insertion per molecule between 1.0 and 2.9 V with using 1 M NaClO4/PC as electrolyte. Na2C6O6 could also show the rechargeable capacity more than 90 mAh g(-1) even in acetylene black free pellets. The good cyclability was also confirmed in Na-ion cells with Na-predoped hard carbon anodes. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:240 / 246
页数:7
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