Thermoelectrically cooled quantum-cascade-laser-based sensor for the continuous monitoring of ambient atmospheric carbon monoxide

被引:63
作者
Kosterev, AA
Tittel, FK
Köhler, R
Gmachl, C
Capasso, F
Sivco, DL
Cho, AY
Wehe, S
Allen, MG
机构
[1] Rice Univ, Rice Quantum Inst, Houston, TX 77251 USA
[2] Bell Labs, Lucent Technol, Murray Hill, NJ 07974 USA
[3] Phys Sci Inc, Andover, MA 01810 USA
关键词
D O I
10.1364/AO.41.001169
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We report the first application of a thermoelectrically cooled, distributed-feedback quantum-cascade laser for continuous spectroscopic monitoring of CO in ambient air at a wavelength of 4.6 mum. A noise-equivalent detection limit of 12 parts per billion was demonstrated experimentally with a 102-cm optical pathlength and a 2.5-min data acquisition time at a 10-kHz pulsed-laser repetition rate. This sensitivity corresponds to a standard error in fractional absorbance of 3 x 10(-5). (C) 2002 Optical Society of America.
引用
收藏
页码:1169 / 1173
页数:5
相关论文
共 10 条
[1]   New frontiers in quantum cascade lasers and applications [J].
Capasso, F ;
Gmachl, C ;
Paiella, R ;
Tredicucci, A ;
Hutchinson, AL ;
Sivco, DL ;
Baillargeon, JN ;
Cho, AY ;
Liu, HC .
IEEE JOURNAL OF SELECTED TOPICS IN QUANTUM ELECTRONICS, 2000, 6 (06) :931-947
[2]  
DLUGOKENCKY E, NATL OCEANIC ATMOSPH
[3]  
Gmachl C, 2000, IEEE CIRCUITS DEVICE, V16, P10, DOI 10.1109/101.845908
[4]   Single-mode tunable, pulsed, and continuous wave quantum-cascade distributed feedback lasers at λ congruent 4.6-4.7 μm [J].
Kohler, Rudeger ;
Gmachl, Claire ;
Tredicucci, Alessandro ;
Capasso, Federico ;
Sivco, Deborah L. ;
Chu, S.N. George ;
Cho, Alfred Y. .
Applied Physics Letters, 2000, 76 (09)
[5]   Trace-gas detection in ambient air with a thermoelectrically cooled, pulsed quantum-cascade distributed feedback laser [J].
Kosterev, AA ;
Tittel, FK ;
Gmachl, C ;
Capasso, F ;
Sivco, DL ;
Baillargeon, JN ;
Hutchinson, AL ;
Cho, AY .
APPLIED OPTICS, 2000, 39 (36) :6866-6872
[6]   Transportable automated ammonia sensor based on a pulsed thermoelectrically cooled quantum-cascade distributed feedback laser [J].
Kosterev, AA ;
Curl, RF ;
Tittel, FK ;
Köhler, R ;
Gmachl, C ;
Capasso, F ;
Sivco, DL ;
Cho, AY .
APPLIED OPTICS, 2002, 41 (03) :573-578
[7]   Cavity ringdown spectroscopic detection of nitric oxide with a continuous-wave quantum-cascade laser [J].
Kosterev, AA ;
Malinovsky, AL ;
Tittel, FK ;
Gmachl, C ;
Capasso, F ;
Sivco, DL ;
Baillargeon, JN ;
Hutchinson, AL ;
Cho, AY .
APPLIED OPTICS, 2001, 40 (30) :5522-5529
[8]   Sensitive absorption spectroscopy with a room-temperature distributed-feedback quantum-cascade laser [J].
Namjou, K ;
Cai, S ;
Whittaker, EA ;
Faist, J ;
Gmachl, C ;
Capasso, F ;
Sivco, DL ;
Cho, AY .
OPTICS LETTERS, 1998, 23 (03) :219-221
[9]   The HITRAN molecular spectroscopic database and HAWKS (HITRAN Atmospheric Workstation): 1996 edition [J].
Rothman, LS ;
Rinsland, CP ;
Goldman, A ;
Massie, ST ;
Edwards, DP ;
Flaud, JM ;
Perrin, A ;
Camy-Peyret, C ;
Dana, V ;
Mandin, JY ;
Schroeder, J ;
McCann, A ;
Gamache, RR ;
Wattson, RB ;
Yoshino, K ;
Chance, KV ;
Jucks, KW ;
Brown, LR ;
Nemtchinov, V ;
Varanasi, P .
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 1998, 60 (05) :665-710
[10]   Room-temperature mid-infrared laser sensor for trace gas detection [J].
Topfer, T ;
Petrov, KP ;
Mine, Y ;
Jundt, D ;
Curl, RF ;
Tittel, FK .
APPLIED OPTICS, 1997, 36 (30) :8042-8049