Controlling the crystal morphology of one-dimensional tunnel structures: induced crystallization of alkane urea inclusion compounds as hexagonal flat plates

被引：12

作者：

Lee, SO ^{[1
]}

Harris, KDM ^{[1
]}

机构：

[1] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 307卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(99)00558-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We propose a general strategy for controlling the crystal morphology of tunnel inclusion compounds in order to induce crystal growth as flat plates rather than long needles. The strategy employs additive molecules designed to selectively inhibit crystal growth along the tunnel direction. The successful application of this strategy is illustrated by the induced crystallization of alkane/urea inclusion compounds as hexagonal flat-plate crystals using 5-octadecyloxyisophthalic acid as the selective crystal growth inhibitor (in the absence of inhibitor, alkane/urea crystals grow spontaneously as long hexagonal needles). (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：327 / 332

页数：6

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