Development of a coupled viscosity-polymerization model for the synthesis of high solids-low viscosity latexes

被引:13
作者
do Amaral, M
van Es, S
Asua, JM
机构
[1] Univ Basque Country, Inst Polymer Mat, Donostia San Sebastian 20080, Spain
[2] Univ Basque Country, Fac Ciencias Quim, Grp Ingn Quim, Donostia San Sebastian 20080, Spain
[3] Surface Specialties UCB, B-1620 Drogenbos, Belgium
关键词
competitive growth; high solids content latexes; molecular modeling; viscosity;
D O I
10.1002/mats.200300009
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The development of a model-assisted methodology for the synthesis of high solids-low viscosity latexes is presented. A simplified polymerization model for systems with a polymerization model was then coupled with an equation for the computation of the viscosity. Their combination resulted in a powerful tool that helped to screen strategies for the synthesis of high solids-low viscosity latexes. Furthermore, using the model-assisted methodology it was possible to determine the workable viscosity boundary for a given formulation. The evolution of the viscosity with the volume fraction was calculated for different polymerization strategies.
引用
收藏
页码:107 / 114
页数:8
相关论文
共 43 条
[1]  
Araújo PHH, 2001, MACROMOL THEOR SIMUL, V10, P769, DOI 10.1002/1521-3919(20011001)10:8<769::AID-MATS769>3.0.CO
[2]  
2-Z
[3]   ENTRY AND EXIT RATE COEFFICIENTS IN EMULSION POLYMERIZATION OF STYRENE [J].
ASUA, JM ;
DELACAL, JC .
JOURNAL OF APPLIED POLYMER SCIENCE, 1991, 42 (07) :1869-1877
[4]   A new model for radical desorption in emulsion polymerization [J].
Asua, JM .
MACROMOLECULES, 2003, 36 (16) :6245-6251
[5]  
BAUER G, 1994, Patent No. 5349858
[6]  
Becker R, 2000, MACROMOL SYMP, V151, P567, DOI 10.1002/1521-3900(200002)151:1<567::AID-MASY567>3.0.CO
[7]  
2-D
[8]  
BETREMIEUX I, 2001, Patent No. 0148026
[9]   Technological lock-in of large firms since the interwar period [J].
Cantwell, John .
EUROPEAN REVIEW OF ECONOMIC HISTORY, 2000, 4 :147-174
[10]   High solids content latexes with low viscosity [J].
Chu, F ;
Guyot, A .
COLLOID AND POLYMER SCIENCE, 2001, 279 (04) :361-367