Synthesis and characterization of a new vanadium oxide, TMAV(8)O(20)

被引：47

作者：

Chirayil, T ^{[1
]}

Zavalij, PY ^{[1
]}

Whittingham, MS ^{[1
]}

机构：

[1] SUNY BINGHAMTON,CTR MAT RES,BINGHAMTON,NY 13902

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1997年 / 7卷 / 11期

关键词：

D O I：

10.1039/a704624c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrothermal synthesis of V2O5 + TMA + LIOH in a 1:2:1 molar ratio after adjusting the pH with acetic acid to pH 3.3 resulted in the formation of a new vanadium oxide, TMAV(8)O(20). The new vanadium oxide has a monoclinic structure with space group C2/m and lattice parameters: a = 23.655(2), b = 3.5931(3), c = 6.3175(5) Angstrom and beta = 103.060(4)degrees. TMAV(8)O(20) has a layered structure with the vanadium atom in the octahedral sites and tetramethylammonium ions residing in between the vanadium layers.

引用

页码：2193 / 2195

页数：3

共 27 条

[1] AKSELRUD LG, 1989, 12 EUR CRYST M MOSC
[2] INFRARED SPECTRA OF CRYSTALLINE TETRAMETHYLAMMONIUM HALIDES
BOTTGER, GL
GEDDES, AL
[J]. SPECTROCHIMICA ACTA, 1965, 21 (10): : 1701 - &
[3] Vanadium oxides synthesized using the tetramethylammonium ion: An addendum
Boylan, EA
Chirayil, T
Hinz, J
Zavalij, PY
Whittingham, MS
[J]. SOLID STATE IONICS, 1996, 90 (1-4) : 1 - 4
[4] Hydrothermal synthesis and characterization of ''LixV2-delta O4-delta H2O''
Chirayil, T
Zavalij, P
Whittingham, MS
[J]. SOLID STATE IONICS, 1996, 84 (3-4) : 163 - 168
[5] CHIRAYIL T, 1996, MRS P
[6] A new vanadium dioxide cathode
Chirayil, TA
Zavalij, PY
Whittingham, MS
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (09) : L193 - L195
[7] NMe(4)V(3)O(7): Critical role of pH in hydrothermal synthesis of vanadium oxides
Chirayil, TG
Boylan, EA
Mamak, M
Zavalij, PY
Whittingham, MS
[J]. CHEMICAL COMMUNICATIONS, 1997, (01) : 33 - 34
[8] CHIRAYIL TG, UNPUB
[9] STRUCTURE CRISTALLINE DU BRONZE DE VANADIUM CUXV4O11
GALY, J
LAVAUD, D
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1971, B 27 (MAY15): : 1005 - &
[10] MANUKHIN MV, 1988, INORG MAT IZV AKAD N, V24, P186

← 1 2 3 →