Linear framework defects in zeolite mordenite

Framework defect correlations are identified in zeolite mordenite that explain both X-ray powder diffraction anomalies and diffuse intensity features in previously reported electron diffraction data. The c/2 displacement of linear "chains" of framework material parallel to the main [001] channel are shown to selectively suppress and broaden the l = 2n + 1 Bragg reflections, thereby linking these framework defects to observed trends in a number of diffracted intensity ratios. At the same time, these defects are shown to produce thin sheets of diffuse scattering that are restricted to the l = 2n + 1 planes of reciprocal space, features that have been reported in electron diffraction studies of mordenite. An empirical relationship between the defect concentration and the framework aluminum content is also established.