Synthesis and reactivity of the osmium methylidene complex [(C5Me5)Os(=CH2)(dppm)][OTf]

被引：28

作者：

Brumaghim, JL ^{[1
]}

Girolami, GS ^{[1
]}

机构：

[1] Univ Illinois, Sch Chem Sci, Urbana, IL 61801 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 11期

关键词：

D O I：

10.1039/a901644i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of the hydride complex (C5Me5)Os(dppm)H, [dppm = bis(diphenylphosphino)methane] with 2 equivalents of methyl trifluoromethanesulfonate (MeOTf) affords the methylidene complex [(C5Me5)Os(=CH2)(dppm)][OTf]; the molecular structure and dynamic NMR behavior of this methylidene complex are described.

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页码：953 / 954

页数：2

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