A nucleobase-inorganic hybrid polymer consisting of copper bis(phosphopentamolybdate) and cytosine

被引：33

作者：

Weng, JB

Hong, MC ^{[1
]}

Liang, YC

Shi, Q

Cao, R

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

[2] Fujian Teachers Univ, Dept Chem, Fujian 350007, Peoples R China

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 03期

关键词：

D O I：

10.1039/b111457n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A nucleobase-inorganic hybrid polymer built from P2Mo5O23 and Cu(II)-cytosine subunits has been prepared; X-ray crystal structure analysis reveals the cytosine molecules weakly coordinate to copper(II) and connect the P2Mo5O23 subunit through hydrogen bonds to form extended 2D networks with complicated hydrogen bonding modes; a bathochromic shift, compared to free cytosine, can be observed in the fluorescence spectra of the hybrid polymer.

引用

页码：289 / 290

页数：2

共 31 条

[1]

Balkus KJ, 1997, STUD SURF SCI CATAL, V105, P415

[2]

Buschmann WE, 1998, ANGEW CHEM INT EDIT, V37, P781, DOI 10.1002/(SICI)1521-3773(19980403)37:6<781::AID-ANIE781>3.0.CO

[3]

2-Z

[4]

BUSHMANN WE, 1998, ANGEW CHEM, V110, P813