Coverage-dependent azimuthal alignment of SO2 on Ag(110)

被引：12

作者：

GutierrezSosa, A

Walsh, JF

Muryn, CA

Finetti, P

Thornton, G

Robinson, AW

DAddato, S

Frigo, SP

机构：

[1] UNIV MANCHESTER,INTERDISCIPLINARY RES CTR SURFACE SCI,MANCHESTER M13 9PL,LANCS,ENGLAND

[2] UNIV MANCHESTER,DEPT CHEM,MANCHESTER M13 9PL,LANCS,ENGLAND

[3] UNIV LIVERPOOL,INTERDISCIPLINARY RES CTR SURFACE SCI,LIVERPOOL L69 3BX,MERSEYSIDE,ENGLAND

[4] UNIV WISCONSIN,CTR SYNCHROTRON RADIAT,STOUGHTON,WI 53589

[5] UNIV WISCONSIN,DEPT PHYS,STOUGHTON,WI 53589

来源：

SURFACE SCIENCE | 1996年 / 364卷 / 01期

基金：

英国工程与自然科学研究理事会; 美国国家科学基金会;

关键词：

chemisorption; low index single crystal surfaces; models of surface chemical reactions; near edge extended X-ray absorption fine structure (NEXAFS); silver; sulphur dioxide; surface chemical reaction; surface thermodynamics;

D O I：

10.1016/0039-6028(96)00727-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The polarisation dependence of S R-edge NEXAFS has been used to study the adsorption geometry of SO, on Ag(110). The molecular plane is azimuthally aligned along the [001] azimuth at 1/3 monolayer coverage, but rotated from [001] by about 55 degrees at 1/2 monolayer, with the molecule upright at both coverages.

引用

页码：L519 / L524

页数：6

共 19 条

[1] CHEMISORPTION AND MULTILAYER ADSORPTION OF SO2 ON AG(111) AND AG(110) [J].