Electrochemical doping of pure single-walled carbon nanotubes used as supercapacitor electrodes

被引：109

作者：

Kimizuka, Osamu ^{[2
]}

Tanaike, Osamu ^{[1
]}

Yamashita, Junya ^{[1
]}

Hiraoka, Tatsuki ^{[1
]}

Futaba, Don N. ^{[1
]}

Hata, Kenji ^{[1
]}

Machida, Kenji ^{[3
]}

Suematsu, Shunzo ^{[3
]}

Tamamitsu, Kenji ^{[3
]}

Saeki, Susumu ^{[2
]}

Yamada, Yoshio ^{[2
]}

Hatori, Hiroaki ^{[1
,2
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058569, Japan

[2] Univ Fukui, Fac Engn, Fukui 9108507, Japan

[3] Nippon Chemi Con Corp, Takahagi 3188505, Japan

来源：

CARBON | 2008年 / 46卷 / 14期

关键词：

D O I：

10.1016/j.carbon.2008.08.026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Pure single-walled carbon nanotubes (SWCNTs) with little bundling show an excellent capacitor performance attributable to the intrinsic nature of the SWCNTs, and possess unusual electrochemical properties characterized by a butterfly shaped cyclic voltammogram which differs from those for conventional activated carbon electrodes. Electrochemical doping in semi-conductor nanotubes occurred at the interface between the electrolyte and the SWCNT surface. In situ measurements showed a remarkable increase of electric conductivity with the polarization from the flat band potential. Because of the potential dependence, the capacitance of the SWCNT electrodes was higher at the higher charging potentials. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：1999 / 2001

页数：3

共 9 条

[1] Solid-state electrochemistry of the Li single wall carbon nanotube system [J].

Claye, AS ;

Fischer, JE ;

Huffman, CB ;

Rinzler, AG ;

Smalley, RE .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (08) :2845-2852

[2] Nanotubular materials for supercapacitors [J].

Frackowiak, E ;

Jurewicz, K ;

Delpeux, S ;

Béguin, F .

JOURNAL OF POWER SOURCES, 2001, 97-8 :822-825

[3] 84% Catalyst activity of water-assisted growth of single walled carbon nanotube forest characterization by a statistical and macroscopic approach [J].

Futaba, DN ;

Hata, K ;

Namai, T ;

Yamada, T ;

Mizuno, K ;

Hayamizu, Y ;

Yumura, M ;

Iijima, S .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (15) :8035-8038

[4] Shape-engineerable and highly densely packed single-walled carbon nanotubes and their application as super-capacitor electrodes [J].

Futaba, Don N. ;

Hata, Kenji ;

Yamada, Takeo ;

Hiraoka, Tatsuki ;

Hayamizu, Yuhei ;

Kakudate, Yozo ;

Tanaike, Osamu ;

Hatori, Hiroaki ;

Yumura, Motoo ;

Iijima, Sumio .

NATURE MATERIALS, 2006, 5 (12) :987-994

[5] POLYANILINE - A HISTORICAL SURVEY [J].

GENIES, EM ;

BOYLE, A ;

LAPKOWSKI, M ;

TSINTAVIS, C .

SYNTHETIC METALS, 1990, 36 (02) :139-182

[6] Water-Assisted Highly Efficient Synthesis of Impurity-Free Single-Walled Carbon Nanotubes [J].

Hata, K ;

Futaba, DN ;

Mizuno, K ;

Namai, T ;

Yumura, M ;

Iijima, S .

SCIENCE, 2004, 306 (5700) :1362-1364

[7] Electrochemical characterization of films of single-walled carbon nanotubes and their possible application in supercapacitors [J].

Liu, CY ;

Bard, AJ ;

Wudl, F ;

Weitz, I ;

Heath, JR .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 1999, 2 (11) :577-578

[8] A STUDY OF THE ELECTROCHEMICAL PROPERTIES OF CONDUCTING POLYMERS FOR APPLICATION IN ELECTROCHEMICAL CAPACITORS [J].

RUDGE, A ;

RAISTRICK, I ;

GOTTESFELD, S ;

FERRARIS, JP .

ELECTROCHIMICA ACTA, 1994, 39 (02) :273-287

[9] Electric double layer capacitance of highly pure single-walled carbon nanotubes (HiPco™ Buckytubes™) in propylene carbonate electrolytes [J].

Shiraishi, S ;

Kurihara, H ;

Okabe, K ;

Hulicova, D ;

Oya, A .

ELECTROCHEMISTRY COMMUNICATIONS, 2002, 4 (07) :593-598

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