Giant vesicles undergoing alkylation reactions observed by optical microscopy

被引:9
作者
Jaeger, DA [1 ]
Clark, T [1 ]
机构
[1] Univ Wyoming, Dept Chem, Laramie, WY 82071 USA
关键词
D O I
10.1021/la011803i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Giant vesicles (GVs) of functionalized, double-chain surfactant 1 (2-hydrazino-N-methyl-N,N-didodecyl2-oxoethanaminium bromide) were observed by phase-contrast optical microscopy as they underwent chemical reactions with 2 (O-methyl S-benzyl phenylphosphonothioate) in a pH 9.0 borate buffer at 23 degreesC. The GVs were damaged and ultimately converted into oil-like droplets. Also, GVs of 1 containing fluorescent dye 7 (1-methyl-7-hydroxyquinolinium iodide) were observed by simultaneous optical and epifluorescence microscopy as they underwent reactions with 2. The reactions effected the loss of 7 from the GVs.
引用
收藏
页码:3495 / 3499
页数:5
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