Synthesis of a side chain liquid crystalline polymer containing the cholesteryl moiety via ROP and "click" chemistry

被引：31

作者：

Cui, Zhenhua ^{[1
]}

Zhang, Yang ^{[1
]}

He, Shangjin ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Minist Educ, Key Lab Funct Polymer Mat, Tianjin 300071, Peoples R China

来源：

COLLOID AND POLYMER SCIENCE | 2008年 / 286卷 / 13期

基金：

中国国家自然科学基金;

关键词：

click chemistry; ring-opening polymerization (ROP); side chain liquid crystalline polymer;

D O I：

10.1007/s00396-008-1916-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Propargyl monocholesterylsuccinate (ChPS) was prepared through the esterification of monocholesterylsuccinate with propargyl alcohol, and poly(3-azidomethyl-3-methyloxetane) (PAMMO) was synthesized via cationic polymerization, using boron trifluoride etherate as catalyst and benzyl alcohol as initiator in methylene chloride. Through the copper-catalyzed "click" reaction between the azide group on PAMMO and the alkyne group on ChPS, a side chain liquid crystalline polymer containing the cholesteryl moiety (Ch-SCLCP) was obtained. The "click" reaction was confirmed by IR, (1)H NMR, (13)C NMR, and GPC studies. The resulting polymer showed thermotropic mesophase as judged by polarized optical microscopy (POM) and differential scanning calorimetry (DSC).

引用

页码：1553 / 1559

页数：7

共 45 条

[1] Synthesis, chiroptical properties and photoinduced birefringence of optically active methacrylic copolymers bearing side-chain bisazoaromatic moieties [J].

Angiolini, Luigi ;

Benelli, Tiziana ;

Giorgini, Loris ;

Mauriello, Francesco ;

Salatelli, Elisabetta ;

Bozio, Renato ;

Dauru, Alessandro ;

Pedron, Danilo .

EUROPEAN POLYMER JOURNAL, 2007, 43 (08) :3550-3561

[2] Combining ring-opening metathesis polymerization (ROMP) with sharpless-type "click" reactions: An easy method for the preparation of side chain functionalized poly(oxynorbornenes) [J].

Binder, WH ;

Kluger, C .

MACROMOLECULES, 2004, 37 (25) :9321-9330

[3] Synthesis and characterization of novel mesogen-jacketed liquid crystalline miktoarm star rod-coil block copolymer [J].

Chen, JF ;

Wang, XZ ;

Liao, XJ ;

Zhang, HL ;

Wang, XY ;

Zhou, QF .

MACROMOLECULAR RAPID COMMUNICATIONS, 2006, 27 (01) :51-56

[4] HIGH-RESOLUTION LASER-ADDRESSED LIQUID-CRYSTAL POLYMER STORAGE DISPLAYS [J].

COLES, HJ ;

SIMON, R .

POLYMER, 1985, 26 (12) :1801-1806

[5] Click chemistry as a powerful tool for the construction of functional poly(p-phenyleneethynylene)s:: Comparison of pre- and postfunctionalization schemes [J].

Englert, BC ;

Bakbak, S ;

Bunz, UHF .

MACROMOLECULES, 2005, 38 (14) :5868-5877

[6] A click approach to unprotected glycodendrimers [J].

Fernandez-Megia, E ;

Correa, J ;

Rodríguez-Meizoso, I ;

Riguera, R .

MACROMOLECULES, 2006, 39 (06) :2113-2120

[7] Formation of aryl-nitrogen bonds using a soluble copper(I) catalyst [J].

Gujadhur, R ;

Venkataraman, D ;

Kintigh, JT .

TETRAHEDRON LETTERS, 2001, 42 (29) :4791-4793

[8] Dendronized linear polymers via "click chemistry" [J].

Helms, B ;

Mynar, JL ;

Hawker, CJ ;

Fréchet, JMJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (46) :15020-15021

[9]

Huisgen R., 1963, Angew. Chem. Int. Ed, V2, P565, DOI DOI 10.1002/ANIE.196305651

[10] Synthesis of degradable model networks via ATRP and click chemistry [J].

Johnson, Jeremiah A. ;

Lewis, Danielle R. ;

Diaz, David D. ;

Finn, M. G. ;

Koberstein, Jeffrey T. ;

Turro, Nicholas J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (20) :6564-6565

← 1 2 3 4 5 →