Isoprene-Assisted Radical Coupling of (Co)polymers Prepared by Cobalt-Mediated Radical Polymerization

被引：60

作者：

Debuigne, Antoine ^{[1
]}

Jerome, Christine ^{[1
]}

Detrembleur, Christophe ^{[1
]}

机构：

[1] Univ Liege, CERM, B-4000 Liege, Belgium

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 08期

关键词：

block copolymers; cobalt; polymerization; radical coupling; radical reactions; VINYL-ACETATE; BLOCK-COPOLYMERS; POLY(METHYL ACRYLATE); TRIBLOCK COPOLYMERS; POLYSTYRENE; POLYMERS; WATER;

D O I：

10.1002/anie.200804880

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tackling blocks: The isoprene-assisted radical coupling (I-ARC) of polymers prepared by cobalt-mediated radical polymerization (see picture) is the first efficient radical coupling method that is not restricted to short chains. When applied to AB diblock copolymers, I-ARC constitutes a straightforward approach to the preparation of novel symmetrical ABA triblock copolymers. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：1422 / 1424

页数：3

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