Catalysis with a palladium giant cluster: Phenol oxidative carbonylation to diphenyl carbonate conjugated with reductive nitrobenzene conversion

被引：59

作者：

Moiseev, II

Vargaftik, MN

Chernysheva, TV

Stromnova, TA

Gekhman, AE

Tsirkov, GA

Makhlina, AM

机构：

[1] N.S. Kurnakov Inst. Gen. Inorg. C., Russian Academy of Sciences, 117907 Moscow GSP-1

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 108卷 / 02期

关键词：

palladium clusters; oxidative carbonylation; conjugated reactions; phenol; nitrobenzene; diphenyl carbonate;

D O I：

10.1016/1381-1169(95)00292-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Giant palladium-561 clusters were found to be effective in catalysis of the oxidative carbonylation of phenol to diphenyl carbonate, conjugated with the reductive carbonylation and reduction of nitrobenzene under CO pressure.

引用

页码：77 / 85

页数：9

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