Composite polymeric electrolytes based on PMMA-LiCF3SO3-SiO2

被引:6
作者
Ahmad, S
Ahmad, S
Agnihotry, SA
机构
[1] Natl Phys Lab, New Delhi 110012, India
[2] Jamia Millia Islamia, Dept Chem, New Delhi 110025, India
关键词
D O I
10.1007/BF02376598
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Preliminary results on the mechanical, optical and electrical properties of composite gel electrolytes (CGEs) with fumed silica (SiO(2)) as a filler added to gel polymeric electrolyte (GPE) based on PMMA, LiCF(3)SO(3) and PC are presented in this paper. Added fumed silica is seen to enhance the mechanical properties of the GPE without changing the conductivity significantly. The high ionic conductivity (x 10(-3) S/cm), high transmission in the visible region and nominal variance of conductivity and viscosity over a wide temperature window show that these CGEs are potential electrolytes for electrochromic windows (ECWs).
引用
收藏
页码:439 / 443
页数:5
相关论文
共 17 条
[1]   Enhancement of ion dynamics in PMMA-based gels with addition of TiO2 nano-particles [J].
Adebahr, J ;
Byrne, N ;
Forsyth, M ;
MacFarlane, DR ;
Jacobsson, P .
ELECTROCHIMICA ACTA, 2003, 48 (14-16) :2099-2103
[2]   Li+ conducting gel electrolyte for electrochromic windows [J].
Agnihotry, SA ;
Nidhi ;
Pradeep ;
Sekhon, SS .
SOLID STATE IONICS, 2000, 136 (136-137) :573-576
[3]   Composite gel membranes: a new class of improved polymer electrolytes for lithium batteries [J].
Appetecchi, GB ;
Romagnoli, P ;
Scrosati, B .
ELECTROCHEMISTRY COMMUNICATIONS, 2001, 3 (06) :281-284
[4]   GEL ELECTROLYTE FOR SOLID-STATE ELECTROCHROMIC CELL [J].
BOHNKE, O ;
ROUSSELOT, C ;
GILLET, PA ;
TRUCHE, C .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (07) :1862-1865
[5]   FAST-ION TRANSPORT IN NEW LITHIUM ELECTROLYTES GELLED WITH PMMA .2. INFLUENCE OF LITHIUM SALT CONCENTRATION [J].
BOHNKE, O ;
FRAND, G ;
REZRAZI, M ;
ROUSSELOT, C ;
TRUCHE, C .
SOLID STATE IONICS, 1993, 66 (1-2) :105-112
[6]  
*CAB SANM LTD, 1999, TECHN B
[7]   Nanocomposite polymer electrolytes for lithium batteries [J].
Croce, F ;
Appetecchi, GB ;
Persi, L ;
Scrosati, B .
NATURE, 1998, 394 (6692) :456-458
[8]   All polymeric solid state electrochromic devices [J].
De Paoli, MA ;
Casalbore-Miceli, G ;
Girotto, EM ;
Gazotti, WA .
ELECTROCHIMICA ACTA, 1999, 44 (18) :2983-2991
[9]   Conductivity and viscosity of liquid and gel electrolytes based on LiClO4, LiN(CF3SO2)2 and PMMA [J].
Deepa, M ;
Sharma, N ;
Agnihotry, SA ;
Singh, S ;
Lal, T ;
Chandra, R .
SOLID STATE IONICS, 2002, 152 :253-258
[10]   FTIR investigations on ion-ion interactions in liquid and gel polymeric electrolytes:: LiCF3SO3-PC-PMMA [J].
Deepa, M ;
Sharma, N ;
Agnihotry, SA ;
Chandra, R .
JOURNAL OF MATERIALS SCIENCE, 2002, 37 (09) :1759-1765