Two-dimensional polytypism of ''crystalline'' (C(5)Me(5))ReO3

被引：8

作者：

Masciocchi, N ^{[1
]}

Cairati, P ^{[1
]}

Saiano, F ^{[1
]}

Sironi, A ^{[1
]}

机构：

[1] UNIV PALERMO, DIPARTIMENTO CHIM INORGAN, I-90123 PALERMO, ITALY

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 13期

关键词：

D O I：

10.1021/ic951502u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystals of Cp*ReO3 present a rare case of two-dimensional polytypism. They consist of a polytypic packing (in the bc plane) of ordered polar chains of three-legged piano-stool Cp*ReO3 molecules (stacked head-to-tail along the a axis). The two-dimensional polytypism arises from the possibility of building a similar motif both with 2-fold screw axes and inversion centers as packing operators, i.e. from the possibility of packing together neighboring chains of equal or different polarity.

引用

页码：4060 / +

页数：1

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