Application of calcium acetylacetonate to the polymerization of glycolide and copolymerization of glycolide with ε-caprolactone and L-lactide

被引:110
作者
Dobrzynski, P [1 ]
Kasperczyk, J [1 ]
Bero, M [1 ]
机构
[1] Polish Acad Sci, Ctr Polymer Chem, PL-41800 Zabrze, Poland
关键词
D O I
10.1021/ma981969z
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The polymerization of glycolide and its copolymers with L-lactide was carried out at 150 and 200°C by conventional methods. The copolymer chain microstructure and the trans-esterification process were studied by 1H and 13C NMR spectroscopy, while the thermal properties were determined by differential scanning calorimetry (DSC). Yields of reactions were observed by weighing washed copolymers and by nuclear magnetic resonance (NMR).
引用
收藏
页码:4735 / 4737
页数:3
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